South Africa lost an early wicket on day four of the second Test in Pune after hosts India had forced the follow-on.
Aiden Markram was bowled lbw by Ishant Sharma to leave the Proteas at 1-1 at the Maharashtra Cricket Association Stadium.
Having bundled out South Africa for 275 to take a huge first-innings lead of 326, India decided to enforce the follow-on as they look to clinch the ongoing three-match Test series against the Faf du Plessis-led side with a game to spare.
India are currently leading the series 1-0 after registering a crushing 203-run victory in the first Test in Visakhapatnam.
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